I personally check the Alerts-tab first. Then I move on to the To-Do list. After that I answer new affiliates and look for new articles to read. There is a lot to read at SFI, it will help to improve your knowledge.
I also make sure to check offers at TripleClicks and my Standing Orders.
Once I leave my house in the morning, I make sure to have TripleClicks GiftCards and also my TripleClicks business cards with me and hand them out to anyone I'll meet during the day.